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ADP (ammonium dihydrogen phosphate, NH4H2PO4)

Ammonium dideuterophosphate (ND4D2PO4) Deuterated ammonium dihydrogen phosphate, crystal D ADP is an antiferroelectric synthetic crystal with a TCurie of 240 K, belongs to uniaxial negative single crystals. It has a high electron-optical coefficient and is used in modulators of visible and near-IR radiation (based on the Pockels effect). The value of tg d allows it to be used up to frequencies of several hundred megahertz. To obtain the maximum shift between the ordinary and extraordinary rays, DADP Z-medium plates are usually used (i.e., cut to the optical axis). Spectral region 0.3 - 1.52 µm. Trab \u003d 241 ... 353 K. Disadvantage: low mechanical strength; high hygroscopicity; - TCurie = 240 - 241 K; - absorption index al [1/cm] in the area of the greatest transparency is 5·10-2; - electro-optical coefficient r63 1010, cm/V at T = 293 K and for l = 0.5461 μm it is 10.63, and for l = 0.5893 μm it is 10.50; - e = 30; - tg d = 0.01; - critical (half-wave) voltage Ucr, kV at T = 293 K is 8.5; - optical strength (threshold of surface damage, P = 5 x 102 MW/cm2 when irradiated with a laser at n = 1.06 μm).
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