Physicists at St. Petersburg State University and the A.F. Ioffe Physicotechnical Institute recently completed a study investigating the temperature behavior of a nanostructured gallium-silver alloy (GaAg), which has shown potential for applications in flexible microelectronics devices. This alloy is of interest for a range of practical applications, including flexible robotics, medical instrumentation, and self-healing superconducting contacts. As technology continues to trend towards miniaturization, it's essential to understand the impact of nanostructuring, where dimensions are reduced to the nanometer scale, on the properties of gallium-containing alloys. The effects of size reduction on phase transitions like melting and crystallization in these alloys have not been thoroughly studied, which is a critical fundamental question.

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The researchers published their findings in Physical Acoustics. Nanostructuring of alloys can be achieved by embedding them into solid matrices with nanometer-scale pores, such as porous glasses. In this study, the average pore diameter was 13 nanometers, emphasizing the minuscule scale of these structures. This research demonstrated a significant decrease in the melting temperature range for nanostructured alloys with two different concentrations compared to the melting temperature of a bulk alloy. Moreover, the researchers observed variations in the crystal structure of the alloys based on the relative concentration of gallium and silver.

Elena Charnaya, a professor at the Department of Solid State Physics at St. Petersburg State University, stated, "We have shown a significant decrease in the melting temperature range for nanostructured alloys of two different concentrations compared to the melting temperature of a bulk alloy. A difference in the crystal structure of the alloys was discovered depending on the relative concentration of gallium and silver."

The study was made possible through support from the Russian Science Foundation under the grant "Phase transformations and charge mobility in functional hybrid nanostructures with developed interfaces." This work sheds light on the promising potential of nanostructured gallium-silver alloys and their relevance in advancing various technological applications.